In my 3x8 raised flue I had similar questions. I asked around, talked to my dealers and then decided to use vermiculite. My first look into using vermiculite. led me into Lowes garden dept. There they had small bags and based on how much of a cubic foot they said on the package I calculated the cost. It came to just under $500. I had to find a cheaper vermiculite. I ended up going to a greenhouse supply (catering to professional greenhouses). There I bought 2 large bales that more than filled the void, all for $60.00 total (this was back in 2007, I'll bet prices are now much higher, but i'll also bet the cost compared to the big box stores is similar).
I filled the void, covered it with half bricks and it worked beautifully. If you don't cover it, the draft, especially if you add high pressure AOF will blow much of the vermiculite out the stack.
Find a greenhouse supplier and get your vermiculite there. Order the BIG bags for the best price per cubic foot, I used course rather than fine.
Dave Klish, I recently bought a 2x6 wood fired evaporator from A&A Sheet Metal which I will be converting to oil fired
Now have solar, 2x6 finish pan, 5 bank 7x7 filter press, large water jacketed bottler, and tankless water heater.
Recently bought another Gingerich RO, this one was a 125, but a second membrane was added thus is a 250, like I had.
After running a 2x3, a 2x6, 3x8 tapping from 79 taps up to 1320 all woodfired, now I'm going to a 2x6 oil fired and a 200-425 taps.