No, metabolism and buddy are two very different naturally-occurring off-flavors. Metabolism is most frequently found early in the season, especially in light-colored/flavored syrup -- buddy is an end-of-season phenomenon. Both are (most likely) due to amino acids in the sap that produce the off-flavor when boiled, but they are caused by different amino acids. Metabolism is from nitrogenous amino acids -- buddy is from sulfur-based AA. In both cases they can't be detected until the sap is boiled. Some people can't detect metabolism off-flavor (or smell) very well....others are very sensitive to the flavor (probably this is genetically based). Most everyone can taste buddy. Metabolism happens only occasional, but some sugarbushes are more prone to the problem. Buddy will happen every year if you collect really late-season sap.