5/16" tubing will develop natural vacuum if installed properly. This has been known for some time.
https://ecommons.cornell.edu/bitstre...=1&isAllowed=y It is more difficult in some ways, requires more taps per lateral line, is less consistent, and the vacuum will "collapse" at certain times and not persist well during low or no flow periods, but it certainly can be done.
3/16" tubing will develop natural vacuum much faster and will retain it far longer during a flow. This is because the internal diameter of 3/16" tubing is small enough that a column can develop (due to cohesion of water) and be held within the tubing. That's not the case with 5/16" tubing, in which the water (sap) column will naturally drain unless maintained by continuous flow of sap.
The biggest advantage with 5/16" natural vacuum systems over 3/16" is that there is less clogging.